Polycarboxylate Polyether Monomer

Custom Polycarboxylate Polyether Monomer Manufacturer

Zibo Zhuoxing Enterprises Co., Ltd was established in 2008 and has been exporting TPEG, HPEG, EPEG, 50% polycarboxylate water reducer liquid and polycarboxylate water reducer powder to many countries since 2015.

Strong Production Ability

The company currently has a full set of production lines from HPEG to PCE high-efficiency water reducers. The annual production capacity is 80,000 tons and the output is 72,000 tons. The total annual PCE production capacity is 100,000.00 tons.

 

Quality Control

The company has passed ISO9001 quality management system certification. We conduct raw material inspection upon entry to ensure qualification for production, effectively control the whole production process to meet requirements, and sample test each batch before delivery.

Professional Team

The company is privileged to have a professional export team. Our R & D team, which consists of a group of highly qualified and experienced experts, maintains close and fruitful communication with renowned scientific research institutes consistently.

Rich Experience

As one of the two earliest manufacturers of TPEG/HPEG in China, after 16 years of continuous research, we have solved many professional needs of domestic and foreign customers in the field of PCE high-efficiency water reducers.

 

Definition of Polycarboxylate Polyether Monomer

 

Polycarboxylate polyether monomer is a kind of main raw material (polycarboxylate ether monomer) for producing high-performance water-reducing type and slump retention type polycarboxylate superplasticizer (PCE), it is produced with isopentenyl and ethylene epoxide as main raw materials.

  • EPEG 3000
    EPEG 3000

    EPEG 3000 is a kind of main raw material (polycarboxylate ether monomer) for producing  Polycarboxylate superplasticizer with excellent slump retention and good adaptability. It is produced with
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  • Raw Material Polycarboxylate Superplasticizer TPEG
    Raw Material Polycarboxylate Superplasticizer TPEG

    1. high durability2.less slump loss3.good concrete fluidity maintenance
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  • Additive material Polyoxyethylene Ether TPEG 2400
    Additive material Polyoxyethylene Ether TPEG 2400

    Additive material Polyoxyethylene Ether TPEG 2400 is a kind of main raw material for producing PCE  1. Appearance: White or light yellow flaky solid  2. Unsaturation mmol/e: ≧0.38  3. Moisture:
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  • HPEG 2400
    HPEG 2400

    HPEG 2400 is produced with methallyl alcohol and ethylene epoxide as main raw materials. The active end group (-OH) and long chain of polyoxyethylene (PEO) in its molecular structure give it
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  • Monomer Polyoxyethylene Ether HPEG
    Monomer Polyoxyethylene Ether HPEG

    Monomer Polyoxyethylene Ether HPEG is produced with methallyl alcohol and ethylene epoxide as main raw
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  • Polycarboxylate Polyoxyethylene Ether HPEG2400
    Polycarboxylate Polyoxyethylene Ether HPEG2400

    polycarboxylate polyoxyethylene ether HPEG2400 has good water solubility and high double bond retention
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  • HPEG For PCE Superplasticizer
    HPEG For PCE Superplasticizer

    Concrete water reducer Polyoxyethylene ether HPEG for PCE superplasticizer is a kind of main raw material for produce PCEAppearance:White or light yellow flaky solidpH Value:5-7Unsaturation:≥
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  • High Water Reducer Series Water Reducer monomer
    High Water Reducer Series Water Reducer monomer

    High Water Reducer Series Water Reducer monomer is suitable for precast and cast-in-place concreteAppearance(25±1℃):White or light yellow flaky solidpH Value(1% water solution):5.0-7.0Unsaturation
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  • Macromonomer For PCE HPEG2400
    Macromonomer For PCE HPEG2400

    Macromonomer For PCE HPEG2400 For PCE with Water Reducing HPEG2400 is applicable for Ready-mix concrete, on-site concrete of industrial or civil buildingsAppearance:White or light yellow flaky solid
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  • Polycarboxylate Ether Copolymer Superplasticizer Flake
    Polycarboxylate Ether Copolymer Superplasticizer Flake

    High Water Reducing Polycarboxylate Ether Copolymer Superplasticizer Flake is main raw material for produce PCE Appearance:White or light yellow flaky solidPh value:5.0-7.0Unsaturation:≥
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  • Polyether Monomer TPEG 2400
    Polyether Monomer TPEG 2400

    Polyether Monomer TPEG 2400 ​has good selectivity,is a kind of main raw material (polycarboxylate ether monomer) for producing high performance water reducing type and slump retention type PCE
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  • Polyether Monomer TPEG 2400 For Polycarboxylate
    Polyether Monomer TPEG 2400 For Polycarboxylate

    Polyether Monomer TPEG 2400 For Polycarboxylate PCE is the basic raw material for high range water reducing admixture - polycarboxylate based superplasticizerAppearance:White or light yellow flaky
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Features of Polycarboxylate Polyether Monomer
 
01/

Improved Workability
One of the main advantages of using polycarboxylate superplasticizer is the improved workability it provides to the concrete mix. This chemical helps in reducing the viscosity of the concrete, making it easier to pour and shape. As a result, construction workers can achieve a higher level of precision and accuracy in their work, leading to better-quality finishes. Furthermore, the enhanced workability also helps in reducing the risk of segregation and bleeding in the concrete mix.

02/

Higher Strength and Durability
Another significant advantage of polycarboxylate superplasticizers is that they contribute to the overall strength and durability of the concrete. By reducing the water content required for a workable mix, these chemicals help in increasing the strength of the concrete. This is especially important in projects that require high-performance concrete with superior strength and durability. Additionally, polycarboxylate superplasticizers also help in reducing the permeability of the concrete, making it more resistant to water and chemical attacks.

03/

Better Flowability
Polycarboxylate superplasticizers are known for their ability to improve the flowability of the concrete mix. This is particularly beneficial in projects that involve intricate structures or have limited access points. The enhanced flowability provided by these chemicals allows the concrete to reach all corners and edges of the formwork easily, ensuring a uniform and consistent finish. In addition, the improved flowability also helps in reducing the risk of honeycombing and voids in the concrete, resulting in a smoother and more aesthetically pleasing surface.

04/

Environmentally Friendly
Another advantage of polycarboxylate superplasticizers is that they are environmentally friendly. These chemicals are water-based and do not contain any harmful solvents or pollutants, making them safe to use in construction projects. In addition, polycarboxylate superplasticizers are also known for their high efficiency, which means that less material is required to achieve the desired results. This not only helps in reducing the overall carbon footprint of the project but also leads to cost savings in the long run.

05/

Enhanced Concrete Strength and Durability
Polycarboxylate superplasticizers are widely used in the construction industry to improve the strength and durability of concrete structures. By reducing water content, these additives increase the density and cohesiveness of concrete, resulting in enhanced compressive strength, flexural strength, and overall durability.

06/

Reduced Water Content
By effectively dispersing cement particles, polycarboxylate superplasticizers allow for a reduced water-cement ratio while maintaining desired workability. This not only boosts concrete performance but also reduces shrinkage potential and improves resistance against chemical attacks.

07/

Self-Compacting Concrete (SCC)
Polycarboxylate superplasticizers play a crucial role in producing self-compacting concrete by ensuring proper dispersion and flow without segregation or bleeding issues. SCC offers numerous advantages such as increased construction speed, improved surface finishes, and reduced labour requirements.

08/

High-performance Concrete (HPC)
In applications where higher strength or exceptional performance is required, polycarboxylate superplasticizers enable the production of high-performance concrete with superior mechanical properties compared to conventional mixtures. This makes it an ideal choice for critical infrastructure projects like bridges or high-rise buildings.

 

Raw Materials for PCE Synthesis

 

Polyether Monomer
According to whether the raw materials used in the production contain unsaturated bonds, polyethers are divided into saturated polyethene glycol ethers and unsaturated polyethene glycol ethers. The most common are HPEG (SPEG) and TPEG (IPEG).

 

Active Monomers
Acrylic acid, methacrylic acid, maleic acid, fumaric acid, itaconic acid, aconitic acid, acetic acid, etc. The most active and most commonly used chemical is acrylic.

 

Functional Monomer
Hydroxyethyl acrylate (2-carboxypropyl acrylate, amine-containing monomers such as acrylamide. Glycol ester monomers, sulfonate-containing monomers and phosphate-containing monomers.

 

Additives To Control The Structure Of PCE
Initiators, commonly used are hydrogen peroxide, ammonium persulfate, and white powder. Inhibitors are commonly used polyphenols such as hydroquinone. Catalyst, commonly used are sodium methoxide and dimethylbenzylamine. Chain transfer agent, used to adjust molecular weight, commonly used substances are sodium methacrylate sulfonate, 2-mercaptoacetic acid, 3-mercaptopropionic acid, etc.

 

PH Value Adjuster
Sodium hydroxide liquid and sodium carbonate solution are commonly used pH adjusters.

 

Polycarboxylate Polyoxyethylene Ether HPEG2400

 

Main Types Of Superplasticizers that Are Commonly Used

Sulphonated Melamine
Formaldehyde Condensates (SME): These are often preferred in the pre-cast industry because they do not dim the cement setting.

 

Sulphonated Naphthalene
● Formaldehyde Condensates (SNF): This is a high range water reducer.
● Modified Lignosulphonates (MLS): Lignosulfonates or sulfonated lignins are water-soluble anionic polyelectrolyte polymers; these are byproducts of wood pulp using sulfite pulping.

 

Polycarboxylate Superplasticizer
Carboxylated Acrylic0Ester Co-Polymers (CAEC): Also known as high-grade water reducers, these are chemicals used when well-dispersed particle suspension is required.

 

Application of Polycarboxylate Polyether Monomer

 

Residential Construction
Utilized in residential buildings for enhancing concrete workability and performance, ensuring durable structures.

 

High-Rise Buildings
Superplasticizers are indispensable in high-rise construction. The reason is the concrete needs to flow and reach considerable heights.

 

Architectural Masterpieces
Complex architectural structures often need superplasticizers to achieve intricate designs. Also, they can help maintain structural integrity.

 

Infrastructure Mega Projects
Large-scale infrastructure projects need superplasticizers. For example, bridges and dams. Superplasticizers can ensure the longevity and performance of concrete structures.

 

Commercial Construction
Employed in commercial projects such as malls, offices, and hotels to improve concrete properties and facilitate efficient construction processes.

 

Infrastructure Construction
Applied in infrastructure projects like bridges, roads, and dams to enhance concrete performance, durability, and sustainability.

 

Industrial Construction
Used in industrial facilities such as factories and warehouses to optimize concrete characteristics and ensure long-term structural integrity.

 

Plastics Industry
Polyether monomers are important raw materials for the preparation of engineering plastics with high temperature resistance, chemical corrosion resistance and high mechanical strength. Among them, polyether ketone plastics are widely used in automobiles, machinery, high-tech electronics and other fields.

 

Coatings Industry
Polyether monomers are important raw materials for the preparation of water-resistant, wear-resistant and chemical-resistant coatings. Polyether monomers can be blended with unsaturated polyester resins to prepare hard coatings for protecting steel structures, building exterior surfaces, etc.

 

Fiber Industry
Polyether monomers can be copolymerized with cyanide-containing fibers to produce high-performance lightweight fibers with excellent high temperature resistance. They are indispensable materials in aviation, aerospace and other fields.

 

Other Fields
Polyether monomers are also commonly used to prepare various new materials with excellent flame retardant, waterproof and wear-resistant properties. For example, in the construction field, polyether monomers are often used as the main raw material to prepare new building materials with acid resistance, alkali resistance, chemical corrosion resistance and good durability.

 

Extract Method Of Polyether Monomer

 

 

Direct Esterification Method

The direct esterification method is a method for preparing polyether monomer by reacting polyether diol with anhydride or acid ester, the reaction conditions are 120-150℃, and the reaction time is 2-4 hours. This method does not require solvent, the reaction steps are simple, but the yield is low, and the waste gas emission is large.

 

Acetal Method

The acetal method is a method for preparing polyether monomer by reacting polyether diol with acetal, the reaction conditions are 150℃ for 4-5 hours. This method does not require the use of a catalyst, and has high yield and less waste gas emission.

 

Epoxidation Method

The epoxidation method is a method for preparing polyether monomer by reacting polyether diol with an epoxidant, the reaction conditions are 8-12 hours at room temperature. This method has the advantages of simple and easy operation and high yield, but the operation process is dangerous and safety measures need to be strengthened.

 

 

Influencing Factors Of The Density Of Polyether

 

Type And Structure Of Polyether Monomer
Different types and structures of polyether monomer have a great influence on the density of polyether. For example, the density of polytetramethylene oxide (PTMO) is about 1.01 g/cm³, while the density of polydimethyl triol ether (PDMS) is only about 0.98 g/cm³.

 

Molecular Weight Of Polyether
Generally, the higher the molecular weight of polyether, the greater the density. This is because high molecular weight will increase the traction of polyether chains and strengthen the intermolecular force so that more molecules can be gathered in a unit volume.

 

Crystallinity Of Polyether
The higher the crystallinity of polyether, the greater the density. Because under the same crystal volume, the greater the density, the smaller the corresponding volume.

 

Oxygen Content
Oxygen content refers to the number of oxygen atoms in polyether. The higher the oxygen content, the higher the density. For example, the density of polyethylene glycol (PEG) is about 1.13 g/cm³, while the density of polypropylene ether (PA) is only about 0.89 g/cm³.

 

 
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Frequently Asked Questions
 

 

Q: What is a polycarboxylate polymer?

A: Polycarboxylates are linear polymers with a high molecular mass (Mr ≤ 100 000) and with many carboxylate groups. They are polymers of acrylic acid or copolymers of acrylic acid and maleic acid.

Q: What is a polycarboxylate polymer monomer?

A: Polycarboxylate superplasticizer monomer particle size and purity will affect the product's Price, and the purchase volume can also affect the cost of Polycarboxylate superplasticizer monomer. A large amount of large amount will be lower. The Price of Polycarboxylate superplasticizer monomer is on our company's official website.

Q: What is the structure of PCE?

A: Polycarboxylate superplasticizers (PCEs) are comb-shaped polymers with an anionic backbone and several nonionic pendant chains, which typically are comprised of polyethene glycols.

Q: What is polycarboxylate powder used for?

A: It is widely used in fluid mortars, such as fluid mortar for pouring, paving, and painting. Besides, it is also commonly used in concrete, including premixed concrete, pump concrete, self-compacting concrete, and many other concretes with high strength and performance.

Q: What is the application of polycarboxylate polymer monomer?

A: This product is mainly used to produce polyhydroxy acid high-performance water-reducing agent series products. It is mainly used in concrete with high requirements for slump retention, such as commercial concrete, mass concrete, self-levelling concrete, etc.; it is also widely used in major national engineering fields such as water conservancy and nuclear power.

Q: What are polycarboxylates used for?

A: Water-soluble linear polycarboxylates are used in household cleaning products, e.g. in laundry detergents, automatic dishwashing detergents and various hard surface-cleaning formulations, and also in institutional and industrial cleaning processes and a variety of technical applications.

Q: What is the maximum percentage of superplasticizers in concrete?

A: The percentages of superplasticizer by weight of cement are limited to1%, 1.25% and 1.5% by individual batch of concrete production.

Q: Why is it important to use PCE in concrete?

A: Polycarboxylate ethers are an essential additive in concrete because they help reduce the water content needed in given workability while increasing the workability of concrete. As a result, this reduces the overall water-cement ratio, improving the strength, permeability, and durability of the concrete.

Q: What is polycarboxylate powder used for?

A: It is suitable for preparing concrete, cement-based, gypsum-based mortar, and other products with high fluidity and strength requirements. Low dosage and high water-reducing rate. The recommended dosage of the cementitious material is 0.1-0.4% (solid content), and the water-reducing rate can reach 25-40%.

Q: What are the advantages of polycarboxylate cement?

A: Polycarboxylate cement (and glass ionomers) exhibits a property called chelation, which is the ability to bond to the Ca ions of the tooth. It is possible that this bond reduces microleakage microorganisms that can cause irritation to the pulp, thus contributing to the cement's biocompatibility.

Q: What is the function of polycarboxylate cement?

A: The original polycarboxylate cement has many desirable characteristics and is still a useful cement for luting crowns and bridges and for lining cavities.

Q: Are polycarboxylates bad for the environment?

A: The mobile, low-MW species of polycarboxylates are accessible to ultimate degradation, as demonstrated in a number of tests, and usually removed before disposal of the sludge. Thus, contamination of ground-water by polycarboxylates is not anticipated.

Q: How should polycarboxylate appear after the mixing process?

A: Expert-Verified Answer. When mixed polycarboxylate cement is mixed correctly, it should have a syrup-like in consistency, which thickens as it sets. One for the few dental fillings that exhibits real adherence to tooth structure is polycarboxylate cement.

Q: What is the biggest advantage of polycarboxylate cement?

A: The advantages of polycarboxylate cement are its ability to bond to tooth structure (one of the first) and its biocompatibility. It is usually used as a luting cement and an intermediate base. its disadvantages are lack of strength and moderate solubility.

Q: What is polycarboxylate admixture?

A: PCE (polycarboxylate-based admixture) is the latest generation of high-performance admixture used to improve the properties of concrete. It is a type of concrete admixture known as high-range water-reducing admixtures or superplasticizers. It is composed of an aqueous copolymer of carboxylic acids.

Q: Are polycarboxylates biodegradable?

A: Polycarboxylates are poorly biodegradable but have a low ecotoxicity. In the sewage treatment plant, the polymer remains largely in the sludge and is separated from the wastewater.

Q: What are the uses of polycarboxylate ethers?

A: What are PCEs used for? PCEs are commonly used in the production of ready-mix concrete, self-compacting concrete, and precast concrete, as well as in the production of dry mortars like self-leveller, flowing screeds and grouts.

Q: What are the properties of polycarboxylate cement?

A: Polycarboxylate cement (and glass ionomers) exhibits a property called chelation, which is the ability to bond to the Ca ions of the tooth. It is possible that this bond reduces microleakage microorganisms that can cause irritation to the pulp, thus contributing to the cement's biocompatibility.

Q: What is the function of polycarboxylate?

A: Usually, polycarboxylate is used. The inclusion of PCE allows for controlling the concrete workability better at lower water to cement ratios. The characteristics of PCE in concrete rely on its amount, where an elevated amount may cause a false setting without any hydration incidence in the concrete

Q: Should I use a superplasticizer?

A: Superplasticizers have several advantages that have led to them gaining popularity recently.
Reduce water content by 25-30% for given workability of water.
When water is scarce, can improve the workability of concrete.
Avoids segregation of concrete.
Allows concrete to be used in concreting heavily reinforced elements.
Increased speed of concreting.

As one of the most professional polycarboxylate polyether monomer manufacturers and suppliers in China, we're featured by quality products and good price. Please rest assured to buy polycarboxylate polyether monomer made in China here from our factory.

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